單項選擇題

用NaOH溶液滴定H3PO4溶液至pH=4.7時,溶液的簡化質(zhì)子條件為()
(H3PO4的pKa1~pKa3分別是2.12、7.20、12.36)

A.[H3PO4]=[H2PO4-]
B.[H2PO4-]=[HPO42-]
C.[H3PO4]=[HPO42-]
D.[H3PO4]=2[PO43-]


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2.單項選擇題已知:H3PO4的pKa1=2.12,pKa2=7.20,pKa3=12.36,調(diào)節(jié)磷酸鹽溶液的pH至6.0時,其各有關(guān)存在形式濃度間的關(guān)系是()

A.[HPO42-]>[H2PO4-]>[PO43-]
B.[HPO42-]>[PO43-]>[H2PO4-]
C.[H2PO4-]>[HPO42-]>[H3PO4]
D.[H3PO4]>[H2PO4-]>[HPO42-]

3.單項選擇題

pH=7.00的H3AsO4溶液有關(guān)組分平衡濃度的關(guān)系應(yīng)該是()
(已知H3AsOpKa1=2.20,pKa2=7.00,pKa3=11.50)

A.[H3AsO4]=[H2AsO4-]
B.[H2AsO4-]=[HAsO42-]
C.[HAsO42-]>[H2AsO4-]
D.[H3AsO4]>[HAsO42-]